Li-Ni ferrite with chemical formula Li0.5−0.5xNixFe2.5−0.5xO4 was prepared by hydrothermal method with different Ni contents (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, and 1.0) using metal chlorides, ferrous sulfate and sodium hydroxide as oxidants. The hydrothermal treatment was accomplished at (155 ∘ C) for (3 h). The required analyses of XRD, FTIR, SEM, TEM, EDX and magnetic hysteresis loop were performed to characterize the complete behavior as a function of x. It was found that lattice constant has a small increase as x increased. Crystallite size had a minimum value of about 13 nm at x = 1.0 and maximum value of about 33 nm at x = 0.3. It was also found that XRD density increased as x was increased. The particle size distributions showed that the maximum value is around 22 nm. FTIR analysis showed the presence of two main peaks with some shifting. Nanospheres were the predominant particles beside the presence of low nanorod concentration. M-H loops had super paramagnetic shape. The coercivity had a minimum value at x = 0.5. The magnetic saturation had a maximum value at x = 0.3, and the initial susceptibility χi had a maximum value at x = 0.5.
Keywords : Li-Ni ferrites Hydrothermal process FTIR spectroscopy Nanostructures Crystalline size
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